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This section features . . .
Radioactive Curves and Calculations
Example:
We
have entered copper-64 (k = - 0.05331), potassium-42 (k = - 0.05776),
and sodium-24 (k = - 0.03850) for 20 hours on the "Graph" menu as our
default example.
Click "Graph" to see the result. Then try the "CalcAge" and
"CalcRate" options.
|
| days |
hours
|
years
|
|
t1/2
=
|
kdays =
|
| iodine-125 |
60 d
|
0.01155
|
iodine-131
|
8 d
|
0.08664
|
lutetium-177
|
6.7 d
|
0.10345
|
phosphorus-32
|
14.3 d
|
0.04847
|
rhenium-186
|
3.8 d
|
0.18240
|
| strontium-82 |
25 d
|
0.02772
|
| strontium-89 |
50 d
|
0.01386
|
xenon-133
|
5 d
|
0.13862
|
|
|
t1/2
= |
khours =
|
bismuth-213
|
0.77 h
|
0.90019
|
copper-64
|
13 h
|
0.05331
|
| Fluoro-deoxy glucose
(FDG) |
2 h
|
0.34657
|
| gallium-67 |
78 h
|
0.00888
|
| molybdenum-99 |
66 h
|
0.01050
|
potassium-42
|
12 h
|
0.05776
|
sodium-24
|
18 h
|
0.03850
|
| technetium-99m |
6 h
|
0.11552
|
| yttrium-90 |
64 h
|
0.01083
|
|
|
t1/2
= |
kyears =
|
cobalt-60
|
0.875 y
|
0.79216
|
cobalt-57
|
0.75 y
|
0.92419
|
carbon-14
|
5730 y
|
0.000121
|
tritium-3
|
12.3 y
|
0.05635
|
|
|
|
seconds
|
t1/2
= |
kseconds
|
krypton-81
|
13 s
|
0.05331
|
|
|
|
|
Half-lives of four common
radioisotopes:

|
Experiment by entering data - the
decay rate k - from
above. Be sure to enter a
negative (-) in the rate representing exponential decay.
|
Warning: Be
sure to enter half-lives with the same units of time - all years, days,
or hours. Otherwise comparisons in one graph are obviously not
valid.
|

|
Background:
|
Plot of carbon-14 decay rate against age
of the sample in years.

Historically known
datable points (Ptolemaic period in Egypt) permited researchers to
verify the concept of radiocarbon dating.
|
Different
radioisotopes have different half-lives. These range from
fractions of a second to billions of years. However, with few
exceptions, the only radioisotopes found in the natural world are those
with long half-lives ranging from millions to billions of years.
In 1947 the chemist Willard Frank Libby developed carbon-14 dating
techniques leading to his Nobel Prize (1960). His methods are now
found in a variety of situations. Carbon-14 has a half-life
of 5,730 years, which may sound like a large number. But on the
scale of existence of the universe, this half-life is quite small
and thus a convenient yardstick for researchers. Carbon-14 dating
is especially popular with anthropoligists seeking to date the age of
bones. There are many other examples. Almost every biology
lab will have a phosphate counter. Physicists have studied
tritium decay seeking to understand fusion on the Sun.
In the medical sciences,
radioisotopes with short half-lives decay so rapidly that detection -
imaging - is
difficult. At the same time, the quality of rapid decay may be
highly desirable for both diagnosis and therapy, e.g.,
chemotherapy. Clearly this is an important research topic.
|
From math class to
data in science and medical labs . . .
Mathematics
texts usually treat both exponential growth (bacterial growth,
population growth, compound interest)
and exponential decay in the same chapter. All are logarithmic
functions. But scientists
traditionally express rate constants as a positive number - though the
rate may represent an exponential decline. Thus we sometimes find
a difference between math texts and science texts in the formula for
decay. Science texts
will have a negative ( - ) in the exponent of the
formula for exponential decay.
Derivation:

|
Radioactive decay
calculation from the AP* Calculus exam:
*AP®
Course Descriptions and various test items. Copyright© 2005
by the College Board.
Reproduced with permission. All rights reserved. <
http://apcentral.collegeboard.com >.
|
|
 |
Useful
Links and Books
|
|
| R.
Chang, Physical Chemistry for
the Biosciences, University
Science Books, 2005, pp. 314-318. |
|
R. E. Dickerson, H. B.
Gray, G. P.
Haight, Chemical Principles,
W. A. Benjamin, 1970, pp. 503-521.
|
For a fascinating discussion of where radioisotopes are
being using in the medical sciences:
< http://www.uic.com.au/nip26.htm
>.
|
For decay as a
function of time:
< http://www.lon-capa.org/~mmp/applist/decay/decay.htm
>. |
For more general
information on radioactive decay:
< http://en.wikipedia.org/wiki/Radioactive_decay
>.
|

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JAVA
animation contributed by
Cindy So
cso133@gmail.com
2006.
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